Ogledwyer0812

RCP26-SSP1 is the pathway among all to have the least economic cost in replacing the snowmelt loss, and the cost would be quadrupled in RCP80-SSP3 scenario by 2100. At a basin scale, the declining snow mass would turn the regional economy to be more vulnerable except Junggar and Ili endorheic basin. The Ertis river and Qaidam endorheic basins display to be most vulnerable. It highlights that the snow value can be economically important in the regions of west China and should be considered more properly in water resources management.We investigated the sedimentary pollution by persistent toxic substances (PTSs) and their potential impacts on the macrobenthic faunal community in the Geum River Estuary, South Korea. Sediment and benthic macrofauna samples were collected from eight sites every two months during the period of February to December in 2015. Target PTSs encompassed metals (Cd, Cr, Cu, Hg, Ni, Pb, and Zn), one metalloid (As), polycyclic aromatic hydrocarbons (PAHs), and alkylphenols (APs). The significant difference to the environment of the inner and outer parts of the estuary (p less then 0.05) was found with relatively high concentrations of PTSs in sediment from the inner estuary. The concentrations of Cu and Zn exceeded the sediment quality guidelines of Korea representing a potential risk to aquatic organisms. The primary source of PAHs was by-products of diesel and gasoline combustion (37%), followed by a coke oven (32%) and oil-burning (31%). The macrofaunal community was spatially distinguished between the inner and outer parts of the estuary (p less then 0.05), regardless of the season. In the inner part of the estuary, the density of the macrofaunal community was high, due to the increased opportunistic species and/or some indicator species (organic polluted or enrichment), implying that the given environment was disturbed. Among the environmental parameters analyzed by the distance-based linear model (DistLM), salinity, chlorophyll-a, and nutrient concentrations were found to be key factors controlling the changes in macrofaunal community structure. Such changes in the closed estuary system would indicate that each taxonomic group had to adjust to lower salinities and alternative food sources. Overall, the distribution of PTSs and macrozoobenthic communities in the Geum River Estuary collectively reflected the environmental gradients caused by surrounding activities in the inner part of the estuary together with direct effects by the irregular inflow of freshwater.The pervasiveness of microplastics, which can absorb pollutants, has a certain impact on pollutant migration in natural waters. Differences in functional groups, such as the hydroxyl group, of pollutants will affect their adsorption on microplastics. In this study, the adsorption of phenanthrene (PHE) or its monohydroxy derivatives, including 1-hydroxyphenanthrene (1-OHP), 2-hydroxyphenanthrene (2-OHP), 4-hydroxyphenanthrene (4-OHP), and 9-hydroxyphenanthrene (9-OHP), on polyvinyl chloride (PVC, measured mean particle size = 134 μm) microplastics was studied. The adsorption efficiency of PHE was shown to be higher than that of either of OHPs. A better fit for pseudo-second-order and Freundlich isotherm models was obtained, indicating different binding sites on the surface of PVC microplastics. KPT-330 The adsorption processes of PHE and OHPs on PVC microplastics were demonstrated to be exothermic and spontaneous. Combined with FT-IR analysis, theoretical calculation, and comparative adsorption experiments, hydrophobic interaction was the dominant mechanism during the adsorption process. In contrast, electrostatic repulsion, CH/π interaction, and halogen bonding played a minor role, to an extent, in the adsorption of PHE/OHPs on PVC microplastics. These findings indicate the influence of the hydroxyl group on adsorption and improve the understanding of interactions between PVC microplastics and PHE/OHPs.Because of their global consumption and persistence, per- and polyfluoroalkyl substances (PFASs), are ubiquitously distributed in the environment, as well as in wildlife and humans. In the present study, we have employed an ex vivo organ culture technique, based on the floating agarose method, of Atlantic cod ovarian tissue to investigate the effects of three different concentrations of PFOS, PFOA (1, 5 and 25 μM) and PFNA (0.5, 5 and 50 μM), used singly and in also in combination (1×, 20× and 100×). In the 1× exposure mixture, concentrations were decided based on their proportional levels (in molar equivalents) relative to PFOS, which is the most abundant PFAS in cod liver from a 2013 screening project. To investigate the detailed underlying mechanisms and biological processes, transcriptome sequencing was performed on exposed ovarian tissue. The number of differentially expressed genes (DEGs) having at least 0.75 log2-fold change was elevated in high, compared to low and medium concentration exposures. The y altered the normal functioning of female gonads, and possibly leading to serious reproductive consequences in teleosts.The toxicological safety of products developed as alternative for conventional plastics (i.e., petroleum derivatives) inevitably demands conducting (eco)toxicological studies. Thus, the aim of the current study was to evaluate the biochemical toxicity of polyethylene microplastics (PE MPs) (representative of conventional MPs) and polylactic acid biomicroplastics (PLA BioMPs) in Aphylla williamsoni larvae used as experimental models. Animals subjected to short exposure to both pollutants (48 h), at environmentally relevant concentration (6 mg/L). At the end of the experiment, different toxicity biomarkers were evaluated. To assess the possible impact of pollutants on the nutritional status of the animals, the total protein, total soluble carbohydrate and triglyceride levels were determined. However, we did not observe differences between the groups, which suggests that PE MPs and PLA BioMPs did not affect the animals' energy metabolism, inducing them to a nutritional deficit. However, larvae exposed to PLA BioMPs have shown increased nitrite and lipid peroxidation levels, which supports the hypothesis that these pollutants increase oxidative stress processes in the animals evaluated, which can affect the animals' physiological homeostasis from different changes. In addition, the decrease in superoxide dismutase activity and of total thiols levels, in these same animals, is suggestive of the impact of PLA BioMPs on the antioxidant defenses, causing a REDOX imbalance, never before reported. On the other hand, decreased AChE activity was only observed in larvae exposed to PLA BioMPs, which demonstrates the anticholinergic activity of the tested polymers; the consequences of which include changes in different neurophysiological functions. Thus, the current study has helped improving the scientific knowledge about impacts caused by PLA BioMPs on freshwater ecosystems, as well as corroborated assertions about the risks posed by such biopolymers on these environments.