Lammbrodersen0437

The high concentrations of precursor vapours within an air mass lead to persistent nucleation with photochemical age ranging from 12 to 48 h in winter. Coincidently, the fast increase of PM2.5 mass was also observed during this range of photochemical age. Noteworthy, CS increased with the photochemical age on NPF days only, which is the likely reason for the observation that the PM2.5 mass increased faster with photochemical age on NPF days compared with other days. The evolution of particles with the photochemical age provides new insights into understanding how particles originating from NPF transform to haze pollution.This study was designed to prepare an adsorbent without any complex modification process for the removal of atrazine (AZN) from aqueous phase. Thus, Mobil composition of matter No. 41 (MCM-41) was synthesized and modified by physical activation at high temperature (650 °C). The synthesized adsorbent was tested by XRD, SEM, EDX, FT-IR and BET to confirm the successful synthesis as well as effectiveness for the adsorption of AZN. The average particle size of prepared material was found to be about 500 nm, while the BET calculations showed that adsorbent was porous with a specific surface area of 25.9 m2/g. Later, it was used in batch removal studies of AZN for which, it showed a high adsorption capacity of 89.99 (mg/g). The pH of 6, temperature of 313 K was found to be the optimized conditions for the maximum removal of AZN. Of the four kinetic models studied, the pseudo-first-order yielded a superior fit in comparison with the other three models. The results indicated that the five linearized adsorption equilibrium isotherm models (Langmuir, Freundlich, Dubinin-Radushkevich, Temkin and Harkins-Jura models) closely correlate the AZN adsorption removal process with Pearson correlation coefficient (R2) values of 0.9955, 0.8551, 0.8736, 0.8913 and 0.7253, respectively. The energy functions obtained by thermodynamic analysis suggested that the AZN sorption follows a non-spontaneous and endothermic path.Analysing the climate envelope of plant species has been suggested as a tool to predict the vulnerability of tree species in future urban climates. However, there is little evidence that the climate envelope of a plant species directly relates to the drought and thermal tolerance of that species, at least not at the resolution required to identify or rank species vulnerability. Here, we attempted to predict drought and thermal tolerance of commonly used urban tree species using climate variables derived exclusively from open-source global occurrence data. We quantified three drought and thermal tolerance traits for 43 urban tree species in a common garden experiment stomatal sensitivity to vapour pressure deficit, leaf water potential at the turgor loss point, and leaf thermal tolerance. We then attempted to predict each tolerance trait from variables derived from the climate envelope of each species, using occurrence data from the Global Biodiversity Information Facility. We found no strong relationships between drought and thermal tolerance traits and climatic variables. Across wide environmental gradients, plant tolerance and climate are inherently linked. But our results suggest that climate envelopes determined from species occurrence data alone may not predict drought or thermal tolerance at the resolution required to select tree species for future urban forests. We should focus on identifying the most relevant strategies and traits required to describe tolerance which in combination with climate envelope analysis should ultimately predict growth and mortality of trees in urban landscapes.Increasing threats to freshwater biodiversity from environmental changes and human activities highlight the need to understand the linkages between biological communities and their environment. Species richness has dominated our view of biodiversity patterns for over a century, but it is increasingly recognized that a trait-based, causal view of biodiversity may be more meaningful than species richness or taxonomic composition. This rationale has led to the exploration of functional diversity (FD) indices to quantify variation in traits that mediate species' contributions to ecosystem processes. In the present study, we quantified FD of fish communities in two large shallow lakes in China with different disturbances level using long-term monitoring data sets. Random-Forests regression was applied to examine how changes in FD were related to natural and human-related environmental variables. Fish stocking, water quality, climate, and hydrological changes were identified as the most important predictors of FD long-term trends. However, the major drivers of FD differed between two lakes, i.e., human activities explaining a greater proportion of FD variance in Lake Taihu, whereas physicochemical environmental factors prominently explained FD variance in Lake Hulun. Moreover, FD indices appeared more sensitive than species richness to multiple disturbances, suggesting that functional traits can be used to detect ecosystem alterations. This study offers insight into how FD can improve our understanding of the associations between fish communities and environmental changes of relevance also for lake and fisheries management.

While distal pancreatectomy with celiac axis resection (DP-CAR) contributes to R0 resection for pancreatic body cancer, arterial blood flow to the liver from gastroduodenal artery is essential. However, in the presence of replaced right hepatic artery (r-RHA), extended DP-CAR (Ex-DP-CAR) in which the right edge of pancreatic resection includes the confluence of gastroduodenal artery (GDA) and proper hepatic artery (PHA) may be feasible. Herein, we report a patient with r-RHA and perform Ex-DP-CAR without reconstruction of PHA.

A 39-year-old man with pancreatic cancer, cT4N0M0 (UICC 8th), underwent DP-CAR after neoadjuvant chemotherapy (NAC). After laparotomy, unlike the evaluation in preoperative imaging, the tumor was found to invade the confluence of GDA and PHA. After confirmation of arterial blood flow to the liver, GDA and PHA was ligated and Ex-DP-CAR was completed with R0 margin status. SR717 The postoperative course was uneventful, with no recurrence 18 months after the surgery.

We performed Ex-DP-CAR with resection of the confluence of GDA and PHA in the presence of r-RHA, which has a potential role in expanding the surgical indications for R0 resection by reducing the risk of ischemic complications without reconstruction of arterial blood supply to the liver.