Campedwards5957

Probing the properties and components of reactive surfaces is crucial for illustrating reaction mechanisms. However, common surface analysis techniques are restricted to in situ acquisition of surface information at the molecular scale in the human environment and industrial catalysis processes. Plasmonic spectroscopies are promising tools to solve this problem. This Feature is intended to introduce the plasmonic core-shell nanoparticle enhanced spectroscopies for qualitatively and quantitatively analyzing surface trace species. Four different working modalities are designed for meeting varied needs, involving in situ surface species detection, catalytic process monitoring, labeled sensing, and dual mode analysis. These newly developed plasmonic spectroscopies show great potential not only in fundamental research but also in practical applications.The proton-conducting performances of a microporous Ti-based metal-organic framework (MOF), MIP-207, were successfully tuned using a multicomponent ligand replacement strategy to gradually introduce a controlled amount of sulfonic acid groups as a source of Brönsted acidic sites while keeping the robustness and ecofriendly synthesis conditions of the starting material. Typically, multivariate sulfonic-based solids MIP-207-(SO3H-IPA)x-(BTC)1-x were prepared by combining various ratios of trimesate 1,3,5-benzenetricarboxylate (BTC) moieties and 5-SO3H-isophthalate (SO3H-IPA). The best sulfonic-MOF candidate that combines structural integrity with high proton conductivity values (e.g., σ = 2.6 × 10-2 S cm-1 at 363 K/95% relative humidity) was further investigated using ab initio molecular dynamics simulations. These calculations supported that the -SO3H groups act as proton donors and revealed that the proton transfer mechanism results from the solvation structure of protons through the fast Zundel/hydronium interconversion along the continuous H-bonded network connecting the adsorbed water molecules.In this work, a convenient and flexible assay for colorimetric and electrochemiluminescence (ECL) sensing of phosphate was proposed based on the enzymatic behavior regulation of the cobalt oxyhydroxide (CoOOH) nanosheet. CoOOH as a novel nanoenzyme exhibited a peroxidase-like activity, which could catalyze different substrates such as 2, 2'-azinobis-3-ethylbenzthiazoline-6-sulfonate (ABTS) and 4-chloro-1-naphthol (4-CN) with hydrogen peroxide (H2O2) as the electron acceptor. Phosphate could specifically regulate the enzymatic behavior of the CoOOH nanosheet via the deactivating effect. A high level of phosphate enabled a weak color change of ABTS, which offered a "turn-off" model of the colorimetric assay with a limit of detection of 0.673 μM. Based on the similar enzymatic behavior, this strategy could then be applied in the ECL assay utilizing l-arginine-6-aza-2-thiothymine-protected gold nanoclusters (Arg-ATT-AuNCs) as ECL signal indicators. Specifically, 4-CN was catalyzed to generate the precipitate and lead to the quenching on ECL emission. Different from colorimetric behavior, phosphate with a high concentration could induce strong ECL performance, which enabled the "turn-on" model of the ECL assay with a more sensitive determination down to 0.434 nM. This flexible enzymatic behavior regulation could then allow the phosphate measurement in environmental samples including tap water and river water with satisfactory accuracy, which holds the potential in the field of environmental protection.Black phosphorus (BP), an emerging remarkable photocatalytic semiconductor, is arousing strong interests in this field of solar-driven CO2 reduction, but its stability and activity are still facing huge challenges. Here, an ambient-stable and effective 2D/2D heterostructure of BP/bismuth tungstate (Bi2WO6) with oxygen vacancy is innovatively designed for syngas production via photocatalytic CO2 reduction. This work, not only resolves the stability problem of BP nanosheets by anchoring ultrasmall platinum (Pt) nanoparticles (∼2 nm) but also greatly improves the charge transfer efficiency by constructing S-scheme 2D/2D heterostructure with coupled oxygen defects. As a result, the generation rates of carbon monoxide (CO) and hydrogen (H2) remarkably reach 20.5 and 16.8 μmol g-1 h-1, respectively, which are much higher than that of reported BP-based materials, and the accomplished CO/H2 ratios (11-21) are exactly the most desirable syngas for industrial applications. Thus, this work constructs an efficient and ambient-stable BP-based photocatalyst for syngas production by CO2 reduction at mild conditions.

Ionizing radiation remains a well-known risk factor of carotid artery stenosis. The survival rates of head and neck cancer patients undergoing radiotherapy have risen owing to medical advancements in the field. Staurosporine manufacturer As a consequence, the incidence of carotid artery stenosis in these high-risk patients has increased.

In this study we sought to compare the outcomes of carotid endarterectomy (CEA) vs carotid artery stenting (CAS) for radiation-induced carotid artery stenosis.

This study was performed according to the Preferred Reporting Items for Systematic reviews and Meta-Analyses guidelines. Eligible studies were identified through a comprehensive search of PubMed, Scopus and Cochrane Central until July 2020. A random-effects model meta-analysis was conducted, and odds ratios (ORs) were calculated. The I-square statistic was used to assess for heterogeneity.

Seven studies and 201 patients were included. Periprocedural stroke, myocardial infarction (MI), and death rates were similar between the two revascularization approaches. However, the risk for cranial nerve (CN) injury was higher in the CEA group (OR, 7.40; 95% CI, 1.58-34.59; I2 = 0%). Analysis revealed no significant difference in terms of long-term mortality (OR, 0.41; 95% CI, 0.14-1.16; I2 = 0%) and restenosis rates (OR, 0.69; 95% CI, 0.29-1.66; I2 = 0%) between CEA and CAS after a mean follow-up of 40.5 months.

CAS and CEA appear to have a similar safety and efficacy profile in patients with radiation-induced carotid artery stenosis. Patients treated with CEA have a higher risk for periprocedural CN injuries. Future prospective studies are warranted to validate these results.

CAS and CEA appear to have a similar safety and efficacy profile in patients with radiation-induced carotid artery stenosis. Patients treated with CEA have a higher risk for periprocedural CN injuries. Future prospective studies are warranted to validate these results.