Knowlesstrauss6992

Relative toxicity estimates based on EC50 ignore the contribution of weak-active components with maximum response below EC50 of the reference standard, especially in complex mixtures or environmental samples. REPs based on an effect level EC10 that can be clearly discriminated from background response are recommended for BEQ calculation. As an example, the aryl hydrocarbon receptor (AhR)-mediated activity of US EPA priority polycyclic aromatic hydrocarbons (PAHs) in RTL-W1 cells was used to assess the reliability of REPs for mixture toxicity prediction based on the effect level EC10.Although pesticides are frequently used for agriculture in the Galapagos Islands (Ecuador), there are, to date, no investigations of pesticide occurrences in its coastal waters. We examined the presence of pesticide residues in the coastal waters of urban areas in two islands of the Galapagos archipelago using a repeated sampling design. Quantification was performed by solid-phase extraction, followed by chemical analysis using liquid chromatography-tandem mass spectrometry (LC-MS/MS) and gas chromatography-electron capture detector (GC-ECD). The diversity and concentration of pesticide residues in Santa Cruz island were higher compared to Isabela island. In total, sixteen pesticides were detected, including three persistent organic pollutants. Carbendazim (23.93 μg·L-1), cadusafos (4.74 μg·L-1), DDT (2.99 μg·L-1), diuron (1.61 μg·L-1) and aldrin (1.55 μg·L-1) were detected with the highest concentrations between samples. Repetitions in locations show that concentrations of pesticide residues varied considerably in space and time. Comparison with local products indicated agricultural activities on the islands as a possible source. PT2977 Furthermore, evaluation through ecological risk quotients showed that the observed concentration levels of seven pesticides pose a relatively high risk for three biotic groups (i.e. algae, invertebrates and fishes). Taken together, this study provides insights into the need to regulate, monitor and assess the presence of pesticides in the islands. At a global scale, this study is moreover valuable for the many islands that are facing the same challenges.Shrub encroachment is occurring in many of the world's drylands, but its impacts on ecosystem structure and function are still poorly understood. In particular, it remains unclear how shrub encroachment affects dryland soil surfaces, including biological soil crust (biocrust) communities. In this study, soil surfaces (0-1 cm depth) were sampled from areas of Grewia flava shrubs and Eragrostis lehmanniana and Schmidtia kalahariensis grasses in the southwest Kalahari during two different seasons (March and November). Our hypothesis is that the presence of different vegetation cover types (shrubs versus grasses) alters the microbial composition of soil surfaces owing to their contrasting microenvironments. The results showed that more significant differences in microclimate (light, soil surface temperatures) and soil surface microbial communities were observed between shrubs and grasses than between sampling seasons. Based on high-throughput 16S rRNA gene sequencing, our findings showed that approximately one third (33.5%) of the operational taxonomic units (OTUs) occurred exclusively in soil surfaces beneath shrubs. Soil surfaces with biocrusts in grass areas were dominated by the cyanobacteria Microcoleus steenstrupii, whereas the soil surfaces beneath shrubs were dominated by the proteobacteria Microvirga flocculans. Soil surfaces beneath shrubs are associated with reduced cyanobacterial abundance but have higher total carbon and total nitrogen contents compared to biocrusts in grass areas. These findings infer changes in the relative contributions from different sources of carbon and nitrogen (e.g. cyanobacterial and non-cyanobacterial fixation, plant litter, animal activity). The distinctive microbial composition and higher carbon and nitrogen contents in soil surfaces beneath shrubs may provide a positive feedback mechanism promoting shrub encroachment, which helps to explain why the phenomenon is commonly observed to be irreversible.Recent large wildfires have caused serious environmental and social impacts in different areas of the world, such as Portugal, Greece and Australia. Sociodemographic changes in rural areas and climate change issues create unprecedented and challenging circumstances that call for an adjustment of fire management strategies and planning tools. In this research, we revise the procedure to assess wildfire susceptibility and hazard for mainland Portugal in a structural perspective. Based on a dataset of burned areas covering 44 years and a set of predisposing factors related to topography and landcover, we tested several susceptibility models using the Likelihood Ratio method, to calculate favourability scores. Landcover classes were analysed using national detailed sources and considering different timeframes. Hazard levels were obtained by combining the susceptibility model with the best accuracy and the probability to burn estimated from fire history (1975-2018). The resulting hazard values were classified in 5 approach and can be complemented by estimations regarding the behavior and severity of wildfires, which should be further explored.Reverse Osmosis (RO) is becoming increasingly popular for seawater desalination and wastewater reclamation. However, fouling of the membranes adversely impacts the overall process efficiency and economics. To date, several strategies and approaches have been used in RO plants and investigated at the laboratory-scale for their effectiveness in the control of different fouling types. Amid growing concerns and stringent regulations for the conservation of environment, there is an increasing trend to identify technologies that are effective in fouling mitigation as well as friendly to the environment. The present review elaborates on the different types of environment-friendly technologies for membrane fouling control that are currently being used or under investigation. It commences with a brief introduction to the global water crisis and the potential of membrane-based processes in overcoming this problem. This is followed by a section on membrane fouling that briefly describes the major fouling types and their impact on the membrane performance.